While the internet is flooded with links claiming "Physical Chemistry by RC Mukherjee PDF Free Download," you must exercise extreme caution. Here is why:
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Most school libraries or coaching institute libraries (Allen, FIITJEE, Aakash) have multiple copies of R.C. Mukherjee. You can borrow the book, scan the specific 5-10 pages you need for a chapter (which is legal under "fair use" for education), and return it. While the internet is flooded with links claiming